Crystal structure of diamine complexonates of cobalt with alkaline-earth cations
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منابع مشابه
AN NMR STUDY OF IONIC SOLVATION OF ALKALINE EARTH CATIONS WITH DIMETHYLSULFOXIDE IN NITROMETHANE SOLUTION
A proton NMR method for the determination of the solvation numbers of alkaline earth cations with dimethylsulfoxide (DMSO) in nitromethane as diluent is described. The method is based on the monitoring of the resonance frequency of DMSO protons as a function of DMSO to metal ion mole ratio while keeping the metal ion concentration constant. The average solvation number of cations at any...
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The interaction between DMSO and alkaline earth perchlorates in anhydrous acetonitrile was investigated by FT-IR spectroscopy. A quantitative study was performed to determine the average number of bonded DMSO molecules using v (SO) and v (C-S) vibrations. Changes in coordination numbers were observed both with increasing atomic numbers and the solvent composition. None of the investigated...
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Cardiac ryanodine receptor (RyR2) function is modulated by Ca(2+) and Mg(2+). To better characterize Ca(2+) and Mg(2+) binding sites involved in RyR2 regulation, the effects of cytosolic and luminal earth alkaline divalent cations (M(2+): Mg(2+), Ca(2+), Sr(2+), Ba(2+)) were studied on RyR2 from pig ventricle reconstituted in bilayers. RyR2 were activated by M(2+) binding to high affinity activ...
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A proton NMR method for the drtermination of salvation numbers of alkaline earth cations with hexamethyl phosphoramide (HMPA) in nitromethane (NM) as diluents is described. The method is based on monitoring the resonance frequency of HMPA protons as a function of HMPA / metal ion molar ratio at constant metalion concentration. The average salvation number of cations, , at any HMPA / metal ...
متن کاملLocal electronic and crystal structure of rare-earth cobalt phosphides RCo2P2 studied by XAFS spectroscopy
The valence state of Ce and Eu was investigated by X-ray absorption near-edge structure (XANES) spectroscopy above L3-Ce and L3-Eu absorption edges in series of RCo2P2 (R = La, Ce, Pr, Eu) magnetic intermetallics. At the same time under similar conditions the rearrangement of Co and Pr local environment vs. temperature was studied by extended X-ray absorption fine structure (EXAFS) spectroscopy...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 1993
ISSN: 0108-7673
DOI: 10.1107/s0108767378093988